J. Phys. Chem. C 130, 4216–4222 (2026)
Deju Zhang, Zhe Wang, Sihang Che, Wei Ji, and Yanning Zhang*
Abstract:
In the field of low-energy-consumption applications, electrical control of magnetism has attracted considerable research attention. Here, we report that the Janus Cr2S2Se monolayer, where Se atoms substitute the upper S layer in the Cr2S3 monolayer, is structural stable. We find that the Janus Cr2S2Se monolayer favors the ferromagnetic configuration with a high Curie temperature of 279 K, and shows semiconducting characteristics with an indirect band gap of 0.44 eV and a valley splitting of 33 meV. By constructing a van der Waals multiferroic heterostructure combined with α-In2Se3 monolayer, its interlayer magnetism can be switched between two types of magnetic coupling via nonvolatile manipulation of the ferroelectric polarization. Our study reveals the switchable magnetism of the Janus Cr2S2Se monolayer, making it promising candidates for use in next-generation low-dimensional spintronics applications.
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